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Rossita Radzak SASER

VOLTAGE CELLS
  1. A simple voltaic cell consists of two different                           Metal
                                                                               K
       metals immersed into an electrolyte.                                    Na
                                                                               Ca
   2. Voltaic cell converts chemical energy to electrical
                                                                               Mg
       energy.                                                                 Al
                                                                               Zn
   3. The more electopositve metal becomes the negative                        Fe       Ease of
                                                                               Sn       releasing
       terminal from which electrons flow.                                     Pb       electrons
   4. The further apart the metals are in the                                  Cu       increases
                                                                               Ag
       Electrochemical Series, the higher the voltage of the
       cell.                                                                  Figure The Electrochemical
                                                                                    Series




                                                               Copper electrode
               Zinc electrode
                                                               Dilute sulphuric acid


                            Figure Voltaic cell using zinc and copper plate

               Observation                                            Explanation
Galvanometer needle deflects                       Electric current is produced due to the flow of
                                                   electrons
Zinc electrode dissolves/ ionized / become         Zinc ionises and becomes Zn2+ ions
thinner.
Bubbles of gas evolve at copper electrode.         Hydrogen gas is produced.

1. Zinc is higher than copper in the Electrochemical Series. Hence a zinc atom releases 2 electrons
to form zinc ion more easily than copper atom. Zinc electrode acts as the negative terminal.

               Zn  Zn2+ + 2e ( oxidation process)

2. The electrons that are released flow through the external circuit towards the copper electrode
which acts as the positive terminal.

3. At copper electrode, the electrons are accepted by the hydrogen ions, H+.

               2H+ + 2e  H2 (reduction process)

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Voltage cell

  • 1. Rossita Radzak SASER VOLTAGE CELLS 1. A simple voltaic cell consists of two different Metal K metals immersed into an electrolyte. Na Ca 2. Voltaic cell converts chemical energy to electrical Mg energy. Al Zn 3. The more electopositve metal becomes the negative Fe Ease of Sn releasing terminal from which electrons flow. Pb electrons 4. The further apart the metals are in the Cu increases Ag Electrochemical Series, the higher the voltage of the cell. Figure The Electrochemical Series Copper electrode Zinc electrode Dilute sulphuric acid Figure Voltaic cell using zinc and copper plate Observation Explanation Galvanometer needle deflects Electric current is produced due to the flow of electrons Zinc electrode dissolves/ ionized / become Zinc ionises and becomes Zn2+ ions thinner. Bubbles of gas evolve at copper electrode. Hydrogen gas is produced. 1. Zinc is higher than copper in the Electrochemical Series. Hence a zinc atom releases 2 electrons to form zinc ion more easily than copper atom. Zinc electrode acts as the negative terminal. Zn  Zn2+ + 2e ( oxidation process) 2. The electrons that are released flow through the external circuit towards the copper electrode which acts as the positive terminal. 3. At copper electrode, the electrons are accepted by the hydrogen ions, H+. 2H+ + 2e  H2 (reduction process)