La réduction des émissions de CO2 est une priorité dans la transition énergétique mondiale. Parmi les pistes envisagées, la capture et réutilisation du CO2 offre d’intéressants avantages tels que la flexibilité de ses solutions et la maturité technique élevée pour plusieurs d’entre elles. Vu le faible coût du carbone en Europe, le déploiement de ces technologies reste lent mais la valorisation du CO2 comme matière première peut améliorer leur rentabilité. Capturer, stocker et utiliser le CO2 représentent de nombreux enjeux ! Pour répondre à ces défis, la plateforme FRITCO2T (Federation of Researchers in Innovative Technologies for CO2 Transformation) a vu le jour à l'Université de Liège en regroupant les expertises complémentaires de 4 laboratoires actifs dans des secteurs aussi divers que la pharmacie, les matériaux de construction, les polymères ou le génie chimique. Cette soirée aura pour but de présenter les activités de la plateforme qui propose une offre de recherche et développement pour la ré-utilisation de CO2 via de nombreuses voies : synthèse de carburants ou de plastiques, utilisation de CO2 comme solvant notamment dans le secteur pharma, carbonatation de matériaux de construction… Des applications concrètes de telles solutions dans le monde industriel seront illustrées et, les exposés seront suivis d'un échange avec un panel animé par Damien Dallemagne (CO2 Value Europe). Les intervenants (orateurs et membres du panel) * Grégoire Léonard, Chargé de cours au Département Chemical Engineering de la Faculté des Sciences Appliquées (ULiège) * Luc Courard, Professeur, Département ArGEnCo - Unité de Recherche Urban and Environmental Engineering, Sciences Appliquées (ULiège) * Brigitte Evrard, Professeur, Département de Pharmacie/Pharmacie Galénique. Centre Interdisciplinaire de Recherche sur le Médicament (ULiège) * Bruno Grignard, Associé de Recherche, Département de Chimie/CERM (ULiège) * Daniel Marenne, Energy Solution Architect (Engie) * Damien Dallemagne, Secretary General (CO2 Value Europe) * Bernard Mathieu, Consultant Indépendant en Durabilité, Spécialiste Industrie du Ciment et Béton (HOP3 Consulting) * Véronique Graff, Directrice Générale (Greenwin)

1. Mardi, 10 décembre 2019
Plein gaz : enjeux et perspectives sur la
valorisation du CO2
Panel d’intervenants

2. Delphine Buchet
Coordination Générale, LIEGE CREATIVE

3. Grégoire Léonard
Chargé de cours au Département Chemical
Engineering, Faculté des Sciences Appliquées (ULiège)

4. 5
Plein gaz : enjeux et
perspectives de la valorisation
du CO2

5. Before talking of CO2…
Steffen W. et al. (2015), Science 347 (6223), 1259855.
6

6. Budget CO2
7
IPCC, SR15 (2018).
1010
500
299
36
1850-1999
2000-2015
Carbon budget
1-year emissions

7. 8
M. Meinshausen, Australian-German Climate & Energy College,
The University of Melbourne, climatecollege.unimelb.edu.au
Are we on the right track?

8. European policy so far
9
0%
20%
40%
60%
80%
100%
0
1000
2000
3000
4000
5000
1990 2000 2010 2020
GHG
Emissions
(Mt
CO
2
eq/y) GHG Emissions - EU-28
Eurostat, 2017. Greenhouse gas emission statistics - emission inventories

9. 10
Boden et al., 2010; EC-JRC/PBL, 2009; European Commission
COM(2011) 112; EEA, 2015
Ambitious objectives for EU
0
1000
2000
3000
4000
5000
1750 1800 1850 1900 1950 2000 2050
MtCO
2
/year
2010
Power and
heat
Industry
Other

10. Belgian position ??
n http://www.fabi.be
11
La Libre Belgique, 16/10/19

11. Trias Energica
Lysen E., The Trias Energica, Eurosun Conference, Freiburg, 1996
12

12. CO2, waste or feedstock?
13
Global CCS Institute. Global Status of CCS 2016: Summary Report.
Koytsumpa et al, 2016. https://doi.org/10.1016/j.supflu.2017.07.029

13. There is C in CO2
14
Source: CO2Chem

14. Large potential for CO2 re-use!
n Up to 18 Gt CO2/y by 2050
15
Hepburn et al., 2019. The technological and economic prospects
for CO2 utilization and removal. Nature 575, 87-97.
https://doi.org/10.1038/s41586-019-1681-6

15. 16
Synthetic Fuels
Mono/Polymers,
Composite and
Biomaterials
Mineralization
Chemical
Transformation
Physical
Use
Pharmaceutics
& Cosmetology
Direct CO2 use
(solvent,
foaming…)
Process sustainability
(LCA and economics)
Sourcing
Capture & Purification
Transversal
The FRITCO2T Platform
www.chemeng.uliege.be/FRITCO2T

16. Success stories
n More than 40 research projects in the last 20 years
n About 12 M€ funding achieved, > 3 M€ unique equipment available
n > 200 publications, patents, communications…
17
From lab to pilot scale High performance analytical tools
CO2-assisted processes

17. Missions of the FRITCO2T Platform
n Market needs, fundamentals push
q Many fundamental problems to be tackled
q Accelerate climbing of the TRL scale
n Lead large-scale research projects
q From regional to european projects
n Support technological developments
q From rationals to new ideas
q Support for operational issues
q Holistic view: Circular economy and life
cycle thinking
18
Industrialisation
Pre-
Industrialisation
Applied
Research
Fundamental
Research

18. Contacts
n CO2 Capture, Power-to-fuels, LCA - TEA
q DCE (G.Léonard, A.Léonard)
n Mono/Polymers, Composite and Biomaterials, CO2
foaming & sCO2 processes
q CERM (Ch. Detrembleur, B. Grignard)
n Mineralization
q UEE (L. Courard)
n Pharmaceutics & Cosmetology
q LTPB (B. Evrard)
19
www.chemeng.uliege.be/FRITCO2T

19. 20
CO2 Capture

20. Purity of sources varies between 0.04% and almost 100%
21
CO2 capture = fluid separation

21. Post-combustion capture
n Usually absorption-regeneration with chemical solvents
22

22. Post-combustion capture
n Boundary Dam, Saskatchewan (2014)
q Coal power plant 160 MWe
q 2700 tCO2/day
=> Flue gas: 180 Nm³/s ; Solvent: 550 L/s
23

23. Post-combustion capture
n Focus: research at ULiège
q Modeling and energy optimization of industrial systems
24
IC: -4%
Split flow: -4%
LVC: -14%
Léonard et al., 2014&2015. DOI:10.1021/ie5036572, DOI:
10.1016/j.compchemeng.2015.05.003

24. Post-combustion capture
n Focus: research at ULiège
q Stability of chemical solvents
25
VOC emissions
CAPEX (corrosion)
OPEX: viscosity, altered properties…
Léonard et al., 2014&2015. DOI:10.1021/ie5036572, DOI:
10.1016/j.compchemeng.2015.05.003

25. Natural gas sweetening
n Process multi-objective optimization
26

26. CO2 market
n CO2 price reaches 25 €/t for large point-source emitters
27
https://markets.businessinsider.com/commodities/co2-emissionsrechte

27. Luc Courard
Professeur, Département ArGEnCo – Unité de
Recherche Urban and Environmental Engineering,
Faculté des Sciences Appliquées (ULiège)

28. CO2 capture for aggregates and concrete
L. Courard, S. Grigoletto, Z. Zhao
Liege Creative, Colonster
December 10th, 2019

29. Principles
n [C3S (alite) – C2S (belite)] + [H2O] → [C3S2H3
(tobermorite) + [Ca(OH)2 (portlandite)]
n Ca(OH)2 + CO2 → CaCO3 + H2O
n Effects
q Compressive strength↑
q Porosity ↓: Ca(OH)2 → CaCO3 with ↑ volume 11%
q pH ↓ due to consumption of Ca(OH)2
30

30. Introduction
n Carbonation can improve specific properties
n If judicious choice of aggregates
q recycled aggregates
q bio-sourced aggregates
zero
► Biomass: zero impact on the
carbon footprint
H.
Nallet
31

31. Objectives
n Study the opportunity of the capture of CO2 in
concrete blocks with miscanthus mineralized
aggregates (insulation) and/or recycled
aggregates
q Mineralization process
q Production of blocks for CO2 capture by means of
accelerated carbonation
q Production of concrete with carbonated RCA
32

32. Materials
n When mixed to inorganic binder: complex interactions
q Absorption of water (up to 70%) and deformation
q Degradation in alkalin medium
q Chemical reactions with carbohydrates affecting setting
mineralization
q transfers aggregates/environment ↘
q durability ↗
q rigidity ↗
q absorption ↘
33
Photo PREFER

33. Materials
Quantity (g) Quantity (wt %)
Miscanthus aggregates 1000 31.12
Cement CEM I 52.5 N 1050 32.68
Water 900 28.01
Superplasticizer 3 0.09
Silica Fume 250 7.78
CaCl2 10 0.31
Figure 8c - Miscanthus after
mineralization
Fi
af
n Fibers soaked in a mineral solution
34

34. Concrete blocks preparation
Quantity
(%)
Quantity
(g/block)
Mineralized miscanthus aggregates 49.18 1335
Cement CEM I 52.5 N 29.51 803
Water 21.31 577
n Composition
n Mixing procedure
1. Mineralized miscanthus aggregates
+ dampening water
2. Cement
3. Mixing water
► Vibration procedure
Vibration table + mass of 8kg, in two times
35

35. n Curing
q Mineralized miscanthus aggregates:
Ambient environment (20°C, 60% R.H.)
Incubator (20% CO2) – 7 hours
q Concrete blocks:
Wet climatic room (21°C, 95% R.H.)
Incubator (20% CO2)
Concrete blocks preparation
48 hours
7 hours
V.
Parmentier
36

36. Results and discussions
n Properties of carbonated concrete blocks
Compressive strength (N/mm²)
CO2 mass gain (%)
Test Wet Curing CO2 Curing
Miscanthus aggregates
1 0.0091 0.0522 1.49
2 0.0091 0.0689 1.14
3 - 0.0546 1.36
Average 0.0091 0.0586 1.33
Carbonated miscanthus aggregates
1 0.0275 0.202 1.43
2 0.0285 0.209 1.23
3 0.0314 0.205 1.37
Average 0.0290 0.205 1.34
x 6 to 7
x 3 to 4
37

37. C&DW deposit evaluation
n Production C&DW (Belgium - Wallonia): 22 Mt/year
n Cement (CEM I type): 800 kg CO2 for 1 T cement (60% CO2 from
decarbonation of limestone CaCO3 = 500kg/T cement
n Capture: 150 kg de CO2/T Recycled Concrete Aggregates
n Preliminary tests (IFFSTAR): 50 kg de CO2/T RCA (natural
process).
38

38. Testing program
n Components
q CEM I 52,5 – SN (EN196-1) - SR
q SR carbonated : 3% [CO2]
(1 month for BL & HO)
(7 days for LAB )
n References
q REF: 100% SN
q SR X BL: x% substitution by Recycled Sand block
q SRC Y HO: y% substitution by Carbonated Recycled Sand SRC beam
q BL = block – HO = beam – LAB = Labocrete
39

39. Water absorption recycled
aggregates
• Treatment: 3% [CO2], 60% RH,
23+/-1°C
• fraction ⇒ [cement paste]
⇒ WA
Concrete Cement (kg/m³)
Block 200 (CEM III/A 42,5)
Hourdis (beam) 320 (CEM I 52,5)
Lab 350 (CEM I 52,5)
4
Durée de carbonatation
40

40. • carbonation time ⇒ WA
Mortar Relative WA decreasing (14
days)
GR LAB 0/2 -51,2%
GR LAB 2/6,3 -31,6%
GR HO 0/2 -44,1%
GR HO 2/6,3 -1%
GR BL 0/2 -92,9%
GR BL 2/6,3 -47,1%
5
• After 28 days :
• GR HO 0/2 : -50,5%
• GR BL 0/2 : -76,9%
Water absorption recycled
aggregates
Durée de carbonatation
41

41. Compressive strength
42
25 % 50 %
SR BL 28j +6 % -5 %
SRC BL 28j +4 % +3 %
SR BL 56j +6 % +4 %
SRC BL 56j +4 % +3 %
25 % 50 %
SR HO 28j -8 % -20 %
SRC HO 28j -4 % -5 %
SR HO 56j -10 % -16 %
SRC HO 56j +1 % -3 %

42. Conclusions
n Use of bio sourced materials like miscanthus requires
a mineralization process;
n Mineralization induces a better resistance to abrasion;
n Carbonation of bio sourced aggregates can increase
concrete blocks performances in terms of compressive
strength;
n Carbonation induces a decrease of RCA absorption;
n Carbonation helps to limit decrease of mechanical
performances of mortars/concrete with RCA.
43

43. References
n CO2 capture for mineralized miscanthus aggregates. S. Grigoletto,
L. Courard, Z. Zhao, F. Michel. International Workshop CO2
Storage in Concrete CO2STO2019. 24-26 June 2019, Marne la
vallée, France (http://hdl.handle.net/2268/234401)
n Improving properties of recycled concrete aggregates by
accelerated carbonation. Z. Zhao, S. Remond, D. Damidot, L.
Courard, F. Michel. ICE Construction materials. Volume 171 Issue
3, June, 2018, 26-132 (http://dx.doi.org/10.1680/jcoma.17.00015)
n Carbonated miscanthus mineralized aggregates for reducing
environmental impact of concrete blocks. L. Courard, V.
Parmentier. Sustainable buildings, 2 (3) (2017), 9p.
(https://doi.org/10.1051/sbuild/2017004)
n Carbonated concrete blocks for CO2 captation. L. Courard, V.
Parmentier, F. Michel. Materialy Budowlane, 10, 2015, p116-118
(DOI 10.15199/33.2015.10.35)
44

44. ERA-MIN Appel 2019 – 12 mars 2020
n Construction materials – Industrial minerals
n Min 3 partners from 2 different countries
n Processing, Production and Remanufacturing
q Increase resource efficiency in resource intensive production processes
q Increase resource efficiency through recycling of residues or
remanufacturing of used products and components
n Recycling and Re-use of End-of-Life Products
q End-of-life products collection and (reverse) logistics
q End-of-life products pre-processing: pre-treatment, dismantling, sorting,
characterization,
q Recovery of raw materials from End-of-life products
45

45. Brigitte Evrard
Professeure, Département de Pharmacie
Pharmacie Galénique, Centre Interdisciplinaire de
Recherche sur le Médicament (ULiège)
Bruno Grignard
Associé de Recherche, Département de
Chimie/CERM (ULiège)

46. 47
Pharmacie et cosmétologie

47. Introduction
48
CO2
73 bars
31°C
Properties of
both liquids
and gases

48. Interesting economic and ecological
properties
49

49. Pharmaceutical applications
• Drug extraction
50

50. Sativex® Prostaserene®
Marketed products
51

51. Pharmaceutical applications
• Drug extraction
• Impregnation
• Sterilization
52

52. n Supercritical CO2 sterilisation of de
méthylprednisolone acetate for Depo-
Medrol® manufacturing.
Marketed products
53

53. Pharmaceutical applications
• Drug extraction
• Impregnation
• Sterilization
• Particles design
• Analytical method:
• Supercritical Fluid Chromatography
• Drug formulation
54

54. SC CO2 for increasing bioavailability
n All drugs go through five stages: liberation, absorption, distribution,
metabolism, and excretion (ADME).
55
Liberation
Absorption
Distribution
Metabolism
Excretion

55. Pharmaceutical applications
• Drug formulation:
• Solid dispersions
• Impregnation
57

56. Impregnation on mesoporous silica
58

57. Pharmaceutical applications
• Drug formulation:
• Solid dispersions
• Impregnation
• Cyclodextrins complexation
• Liposomal formulations
59

58. Patented processes
n CD complexation
n Solid dispersions
60

59. 62
Chimie fine et matériaux

60. CERM key expertise
63
Macromolecular engineering
(Tools, processes, green chemistry, CO2 utilization, LCFP polymers)
Medicine & therapeutics
(Biomaterials, drug delivery systems, implants & scaffolds, diagnosis)
(Smart) materials
(Composites, coatings & adhesives, responsive/shape memory materials)
Energy storage & saving
(Organic cathodes, solid electrolytes for Li-ion batteries, insulation)
Environment
(Degradable/reusable polymers, air/water depollution, EMI shielding)

61. CO2 processes in polymers science
64
q Use of supercritical CO2 to make (industrial) processes greener and/or new products!
Biomaterials
Extrusion - Foaming
Extraction Green solvent

62. CO2 conversion into monomers/chemical
65
q Catalyst design & optimization
q Upscaling (multi-kg)

63. CO2 conversion into polyurethanes (PU)
66
q A C1 building block for polyurethanes with reduced carbon footprint
Shoes mattress Sport flooring
CardyonTM
5,000 ton/year
Elastic fibers

64. CO2 conversion into polyurethanes
67
q New conceptual routes to (isocyanate-free) polyurethanes

65. CO2 conversion into polyurethanes
68
Hydrogels Insulation foams
λ < 50 W/m.k
Self-blowing foams
Ink for 3D
printing
Coatings
Anti-corrosion
Adhesives
> 24 MPa
q New conceptual routes to (isocyanate-free) polyurethanes

66. CO2 conversion into polycarbonates (PC)
69
q Polycarbonates with reduced carbon footprint by a phosgene-free process
1,000 ton/year
Organic glasses

67. CO2 conversion into polycarbonates (PC)
70
q An avenue for innovative sustainable materials: poly(carbonate)s

68. CO2 conversion into polycarbonates (PC)
71
q An avenue for innovative sustainable materials: poly(carbonate)s
Energy storage
High ionic conductivity at r.t.
(3.72 ×10-5 S. cm-1)
Cycling: Up to 400 cycles
D
Li+ or Na+

69. CO2 conversion into polycarbonates (PC)
72
q An avenue for innovative sustainable materials: poly(carbonate)s
Energy storage
High ionic conductivity at r.t.
(3.72 ×10-5 S. cm-1)
Cycling: Up to 400 cycles
D
Li+ or Na+
Tissue engineering
Cells growth
No cytotoxicity
In-vivo testing
Tissue engineering

70. 73
CO2 to fuels

71. CO2 to fuels
n C is a fantastic support for energy storage!
74
Methanol
Batteries Pb
Coal
Ethanol
Diesel
H2 (1 bar)
CH4 (1 bar)
H2 (700 bar)
H2 liquid
Gasoline
0
5
10
15
20
25
30
35
40
45
0 25 50 75 100 125 150
Volume
density
(MJ/L)
Mass density (MJ/Kg)
H2 composite
Batteries Li-Ion
CH4 (250 bar)

72. CO2 to fuels
n Power-to-liquid, power-to-gas
75
=> Sustainability is possible with carbonated fuels!

73. Research at system scale
n Energy model with 100% variable renewables + storage
for electricity grid:
q Based on historical belgian data for load and capacity factors
q Vary the installed capacity to minimize system costs and avoid
black-outs
76
Bortolini E., 2019.

74. Research at system scale
n Energy model with 100% variable renewables + storage
for electricity grid:
77
Bortolini E., 2019.

75. Research at process scale
n Process design
q Electrolysis, CO2 capture and fuel synthesis
q Integration raises efficiency from 40.1 to 53.0% !
78
Léonard et al., 2016. Computer aided chemical engineering 38, 1797.
DOI: 10.1016/B978-0-444-63428-3.50304-0

76. Research at process scale
n Reactor design
q Compact, safe and flexible
79
ACM Reactor
Distillation
column

77. Daniel Marenne
Energy Solution Architect (Engie)

78. Liège Creative
Hydrogen & CCU
Dec 10th 2019

79. 1 Why ENGIE?
2 Why Hydrogen?
3 Why CCU?
0
0

80. Why ENGIE?

81. 84 8
BE WORLD LEADER
IN THE ZERO-CARBON
TRANSITION
“AS A SERVICE”
Faster growth, higher value, better impact
OUR AMBITION

82. 85

83. Why Hydrogen ?

84. 87
0
500
1000
1500
2000
2500
3000
1-janv 1-févr 1-mars 1-avr 1-mai 1-juin 1-juil 1-août 1-sept 1-oct 1-nov 1-déc
Production + Consumption
Consommation (GWh/week) Solar installed 50GWp
Wind installed 9 GWp 50GWp solar + 9GWp éolien
Example: what if electricity production in Belgium would be 100% renewable 80 TWh/year:
• Shortage of electricity in winter period
• Excess of electricity in summer period
Shortage of electricity
Shortage of electricity
Excess of electricity
à Need of H2 to store electricity
FINAL ENERGY DEMAND TWh
2015
Final Energy Demand 396
Solids 18
Oil 166
Natural gas and derived gases 105
Electricity 81
Distributed heat 6
Renewable energy forms 20
Source federal Planning Bureau
Rem Electricity represents 20% of Belgian energy demand
è The challenge is much bigger
than only renewable electricity

85. 88
• Synergies of the large scale electrolyser with power plants
q Grid connection allows additional offtake (e.g. 300 MW)
q Safety Culture and O&M skills adapted to the presence of high voltage equipment and
explosive media
q Knowhow on water chemistry (feedstock equivalent to demin water) and buffering
q Proven experience with 24/7 remote operations (Air Liquide also operates remotely)
q Availability of sufficient cooling.
q Having green hydrogen production coupled with traditional Power station brings a lot
flexibilities, from – P (electrolyser) until + P (Power station)!
• Business Unit “Hydrogen”: focussing on new projects
q Economy of scale to reduce the Capex cost of the electrolyser
q 1 MW at 1000 €/kW à 100 MW at 700 €/kW à 400 MW @ 600 €/kW à so, focus on large
scale electrolyser (or projects that could be scaled up)

86. 89

87. Why Carbon Capture & Use?

88. 91
Belgian final fossil energy demand
Coal : 18 TWh
Gas: 106 TWh
Oil : 166 TWh
Ø 100TWh Road transport
Ø 20 TWh Aviation transport
Ø 46 TWh Water, Railway transport and other
Source federal Planning Bureau
Realistic alternatives
Ø Synthetic CH4 (SNG) can replace Coal & Gas
Ø Electricity (20TWh) and H2 (40TWh) can replace Transport Oil *
Ø Synthetic kerosene can replace Aviation fuel
Ø Synthetic methanol can replace other transport fuels.
* 50% of transport oil replaced by Electricity an 50% by H2
SNG:
Oil Mobility:
Aviation:
Methanol:
Total need including electricity:
Need of green Power:
120 TWh/55% = 218 TWh
20 TWh + 40TWh/65% = 81,5 TWh
20 TWh / 48% = 42 TWh
46 TWh / 55% = 84 TWh
500 TWh green electricity. Belgium needs to import renewable energy!

89. Solar PV
Water
xx m³/hr
Electrolyzer
Liquefaction
Ship
Storage Liq H2
Storage Liq H2 Pressurization
+ Evaporation
Ø Electricity needs to produce H2 (50 kWh/kg)
Ø Electricity needs to liquify H2 (13 kWh/kg)
Ø Total need of electricity 227 TWh
Ø Total installed power of solar in Sahara 75 GW
Ø Total need of demin water 32,5 MT/year. (50 kWh / tH2)
Not existing technology
New assets
Marginal cost* H2 before storage 28,6 €/MWh
* Price of green electricity 15€/MWh
H2 way

90. Solar PV
Ship
Hydrogenation *
+ liquefaction.
Storage LSNG
Water
xx m³/hr
Electrolyzer
Storage LSNG Pressurization
+ Evaporation
New assets
Ø Electricity needs to produce CH4 (218 TWh)
Ø Electricity needs to liquify CH4 (7 TWh)
Ø CO2 needs 20 Mt/year
Ø Electricity need to produce CO2 from DAC 13,5 TWh (no extra need of heat)*
Ø Total Excess water => 4 MT/year ( DAC and CH4 produce water)*
Ø Total need of electricity 238.5 TWh
Ø Total installed power of solar in Sahara 79 GW
Marginal cost** LSNG before existing infra 29,75 €/MWh
Marginal revenues of Water not taken into account..
Direct Air Capture (DAC)
CO2
*based on current Climworks data
** Price of green electricity 15€/MWh
SNG way using CO2 as H2 carrier (CO2 looping)
Existing assets

91. 1500 km² = 40% of province

92. 95
In March ENGIE entered into a Joint
Development Agreement to further
develop a pilot project (2,5 - 5MWe) in
the Port of Antwerp together with its
partners:
• Indaver
• Oiltanking
• Vlaamse Milieu Holding
• Port of Antwerp

93. 96
• H2 production at
Rodenhuize power plant
site (50-300 MWe)
• CO2 capture from steel
gases at Knippegroen site
(up to 500000 tons/year)
• Production of green
methanol at Knippegroen
site – to be used locally in
Port of Ghent
• Current situation: offtaker
and investor for methanol
plant to be found

94. 97
Renewable
Water
CO2
Electrolyzer
Project goals:
1. Be the world first large scale green hydrogen producer (150 MW).
2. Industrialize a Walloon technology of CO2 looping ( Capture but also transport & utilization).
3. Industrialize a biological process of conversion of H2 and CO2 to methane.
Challenge:
Ø Find offtaker willing to pay the cost of green fuel:
Ø Cost of renewable electricity / 55% + 20% (Capex & opex) = (50 /55%) x1,2 = 110 €/MWh
CH4
mobility
Industry

95. daniel.marenne@engie.com

96. Confidential & Proprietary
99
ENGIE has developed into a global end-to-
end energy services provider
160,000
employees
globally
70
countries
€61Bn
revenues
€182M
R&D spend
+100
University
partners
24.8 GW
installed renewable
capacity
1st
globally in cold
distribution
networks
1st
globally
in micro-grids
1st
independent
power producer
in the world
2nd
globally in
electric vehicle
charging
stations
2nd
global supplier
of technical
installation
services
12€Bn
investments in energy
transition over 2019-2021
4th
globally in hot
distribution
network
7-9%
annual average growth by 2021 of
net recurring income group share
€166M
investment in
innovative
start-ups
+1,000
Researchers &
experts in 11
R&D centers

97. Damien Dallemagne
Secretary General (CO2 Value Europe)

98. CO2 Value Europe
Building the Carbon Capture & Utilization
(CCU) industry
10 décembre 2019

99. 1
Carbon Capture & Utilisation… the time is now !

100. 2
5 November 2019
Rotterdam
Carbon Capture & Utilisation… the time is now !

101. 3
CCU… the time is now !

102. 4
, October 2018, Virgin Atlantic and Lanzatech
CCU industry is moving – 10 recent key CCU events
First power-to-gas plant in residential building, project in Augsburg:
when green electricity is stored as natural gas
Feb 2019, Cityworks Augsburg und EXYTRON

103. 5
May 2019
August 2019
May 2019
2 Oct 2019 - REUTERS. Sunfire and French oil
major Total said they will team up on a pilot
project to produce methanol from renewables
and carbon dioxide at the Leuna refinery in
Germany.
CCU industry is moving – 10 recent key CCU events

104. The only European association
dedicated to CO2 Utilisation and
bringing together partners from
the complete value chain
CO2 Value Europe integrates stakeholders from
the complete CCU value chain across industries
Multinational Companies, SMEs, Regional Clusters, Research Institutions, Universities
6

105. 7
Our vision: make CCU a key pillar of the
transition to a sustainable economy
Replacing fossil carbon by
utilization of CO2 as a feedstock for
the chemicals, materials and fuels
industries
Renewable feedstock
Net reduction of global CO2 emissions
from the process industry and from the
transportation sectors
(road, air, maritime)
Climate mitigation
Process efficiency
Renewables Hydrogen
CCS
CCU
Electrification Biomass
Components of a
sustainable economy

106. 8
Our mission: create a scalable carbon recycling
industry
Our
official
mission
statement
Promote the development and market deployment of
sustainable industrial solutions that convert CO2 into valuable
products, in order to contribute to the net reduction of global
CO2 emissions and to the diversification of the feedstock
base.
We want to create a CCU industry sector with scalable
business models for real impact of carbon recycling.

107. 18
Multinational
Industry Leaders
Albioma, Carmeuse,
CRH, DEME, Drax, EEW, Engie,
HeidelbergCement, Indaver,
Keppel Seghers, Lhoist, Saipem,
Solvay, Suez, Terega, Total,
Uniper, Veolia
19
4
26
Clusters
Axelera,
e-PURE,
GreenWin,
Port of Antwerp
Research
Organisations
ACIB, CEA, DIFFER, EPFL, Fraunhofer, ICIQ,
IFP-EN, KIT, LEAP, LEITAT, Nova Institute,
NOVA.ID.FCT, Sotacarbo, Swerim, Tecnalia,
TNO,
U Bologna, UC Louvain, U Gent,
U Liège, U Mons,
U Sevilla, U Sheffield,
U Surrey, VITO, VTT
CO2 Value Europe – the community of CCU pioneers
9
Facts & Figures
✓ Founded: Nov 2017
✓ 67 members and
growing
✓ Seen by EU authorities
as legitimate rep. of
CCU community
✓ Attracting interest from
all over the globe
✓ Creating a completely
new business, turning
CO2 into real products
Specialised SMEs
ACP, AirCapture, Atmostat,
Avantium, Carbon8, Carbon Clean Solutions,
Climeworks, CRI, Econic, EnviroAmbient,
Hydrogenics,
Hysytech, IC2R, IDENER, Inventys, Nordic Blue
Crude, Orbix,
Sunfire, Zeton

108. 10
Our members

109. www.co2value.eu
Contact
Damien Dallemagne
Secretary General
damien.dallemagne@CO2value.eu
+32 488 366 231
www.CO2value.eu

110. Véronique Graff
Directrice Générale (Greenwin)
Bernard Mathieu
Consultant indépendant en Durabilité,
Spécialiste Industrie du Ciment et Béton
(HOP3 Consulting)

111. 200 membres
> 30 GE
> 110 PME
> 16 CRA-W
> 5 Univ.
Portefeuille
de
42 projets
collaboratifs
= +110 Mio €
800 contacts
dans le monde
5 projets
européens
SCOT (CCU - utilisation du CO2
pour les GE et PMES
émettrices de CO2 et
innovantes)
CO2 Value Europe : création
AISBL indus.
LCIP (ACV pour les PMEs)
AGRICHEMWHEY et
FERTIMANURE (pilote indust.
GE + PME en économie
biosourcée )
En moyenne/an:
6 projets labellisés/an
16 Mio € budget/an pour les
projets
2019
+/- 75% entreprises
= 15.000 ETP
42%
43%
15% Chimie
Construction
Performances &
croissance hors
norme:
> Emplois : +20%
> Valeur ajoutée: +40%
©
Pôle
GreenWin
asbl
-
2019
L’énergie d’un réseau pour concrétiser vos rêves d’innovation
industrielle durable #BecauseTheFuturIsNow

112. Ongoing missions for 2 cement
and 1 lime company
A Belgian consultancy with extensive experience in
sustainability and innovation strategies, roadmaps and
management processes
within the industry, NGOs and associations
at regional, national and international level
www.hop3.eu bernard.mathieu@hop3.eu

113. Plein gaz : enjeux et perspectives sur la
valorisation du CO2
Panel d’intervenants

114. LIEGE CREATIVE, en partenariat avec :

115. Et aussi :